Delhi, our capital city, a few months ago was affected by a heavy smog leading to the closure and disruption of many schools and services.Did we ever think such a thing was possible 50 years ago? Numerous reasons can be attributed to this. One of the most prominent reasons is pollution due to the vehicles and industries in and around Delhi .So what is the solution? Everyone simply advised using other non-polluting sources of energy such as solar and wind power. But, is it practical? If using it was so easy and nice, why aren’t people already using them and still rely on fossil fuels? Ponder this. The efficiency of a commercial solar cell is just around 20%, whereas the efficiency of a fossil fuel is around 35%-40%.
The cost of setting up a domestic solar power plant in India is around 1 lakh. Hence, not many have turned towards the alternative of solar power. So, let’s discuss why solar energy is so expensive to be implemented domestically. Solar cells are made of semiconductors such as Si, Ga, GaAs etc. Classification of materials into metals, semiconductors and insulators is based on their increasing band energy gap. The challenge for scientists here is to produce a material which can give us higher efficiency and at the same time is economically viable. Naturally occurring semiconductor materials are usually indirect band gap materials.(Read more about indirect band gap) Usually Indirect band gap is smaller than the direct band gaps. But indirect band gap materials require phonons (Read more about phonons) and solar energy as well for the electrons to jump from the valence band to the conduction band.This poses a problem.The direct band gap is sometimes too big for solar energy and the indirect ones require phonon assisted transition. Here, we are required to find a material in the Goldilocks zone (something just right for solar power) or a combination of materials .The highest ever theoretical efficiency achieved is 33.16% using multi-junction solar cells. But this was done under laboratory conditions and might not be commercially viable. So, this was about photo-voltaic cells. Another way to tap in solar energy is using isomeric organic molecules which can store energy. Cis-trans isomers of azobenzene are used .
There is an energy difference between the cis and trans isomer which is used to store the obtained solar energy.The number of times this can be done is quite low. Hence this is seen to be an nonviable solution. The attachment of carbon nano-tubes to the molecules helped improve the properties a bit. Similar materials with activation energy in the UV-visible region of electromagnetic spectra can be used. (Ongoing research at MIT Boston by Prof. Jeff Grossman) But can these materials be put for commercial use ? This is huge question .These are some of the reasons why we cannot eliminate the use of fossil fuels completely and start relying on solar energy immediately.